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Aldrich
Silver trifluoromethanesulfonate
176435 -
≥99%
DOWNLOAD MSDS (PDF)Synonym: Silver triflate, Trifluoromethanesulfonic acid silver salt
CAS Number: 2923-28-6
Linear Formula: CF3SO3Ag
Molecular Weight: 256.94
Beilstein Registry Number: 3598402
EC Number: 220-882-2
MDL number: MFCD00013226
PubChem Substance ID: 24850578
Properties
| Related Categories | Catalysis and Inorganic Chemistry, Chemical Synthesis, Gold Catalysis, Silver, Silver Additives |
| assay | ≥99% |
| mp | 286 °C(lit.) |
Description
Packaging
1, 10, 25 g in glass btl
Application
Gold Catalysts — 21st Century ′Gold Rush′
Yields olefins from secondary phosphates and thiophosphates. Using this reagent the etherification of alcohols with primary alkyl halides can be accomplished under mild conditions.
Used to generate cationic rhodium catalysts from chlororhodium complexes for the hydrophosphination of acetylenes. Also employed as a catalyst for the preparation of silyl ethers by hydrosilylation of aldehydes.
Price and Availability
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Documents
Certificate of Analysis
Certificate of Origin
| FT-IR Condensed Phase |  |
| FT-IR Raman | |
| ChemFiles Vol 6 No 2 (1 MB ) |
| Structure Search |  |
| Similar Products |
Safety Information
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | dust mask type N95 (US), Eyeshields, Gloves |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36 |
| WGK Germany | 3 |
Technical information & documentation associated with this product is available in the Safety & Documentation tab.
Articles
Fluorinating Reagents
The importance of selectively fluorinating compounds in medicinal chemistry, biology, and organic synthesis is well appreciated and provides a major impetus to the discovery of new and mild fluorinat...
Aldrich ChemFiles 2006, 6.2, 5.
Keywords: Fluorinations, Medicinal chemistry, Metathesis, Organic synthesis, PAGE
Gold Catalysis
Gold catalysis is playing an increasing role in organic synthesis for the facile construction of complex architectures not readily accessed by standard methods. Gold catalysts mediate unique C–C, C–O...
Aldrich ChemFiles 2007, 7.5, 10.
Keywords: Catalysis, Enyne rearrangements, Heterocycle formation, Isomerizations, Organic synthesis, Rearrangements
Intramolecular Hydroamination
An example of the potency of gold catalysis in hydroamination reactions was highlighted in 2006 by Crawley and Funk in the multistep synthesis of communesin B.1 One of the key steps in the synthesis ...
William Sommer
Aldrich ChemFiles 2009, 9.5, 3.
Keywords: Catalysis, Hydroaminations
Related Content
Gold Catalyst in Chemical Synthesis
Introduction Hashmi, Toste, Echavarren, and Haruta, among others, have fueled the advance of gold into the forefront of transition metal catalysis.1,2 Phosphine ligated gold(I) complexes have risen a...
References
Tetrahedron Lett. 36, 719, (1995)
Tetrahedron Lett. 35, 8111, (1994)
J. Org. Chem. 71, 9248, (2006) Abstract
Chem. Commun. (Camb.), 1359, (2006)
Beil. 3,IV,34
Fieser 6,520 / Fieser 7,324 / Fieser 9,414 / Fieser 12,435 / Fieser 13,274 / Fieser 14,282 / Fieser 16,302 / Fieser 17,314
Aldrich MSDS 1, 1604:D / Corp MSDS 1 (2), 3099:C / FT-IR 2 (1), 1506:C / FT-IR 1 (2), 1231:C / IR-Spectra (3), 533:E / RegBook 1 (1), 1055:L / Sigma FT-IR 1 (2), 947:D / Structure Index 1, 163:B:9
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